Graph of Temperature Versus Equilibrium(Kq) for Ammonia Production
Ammonia is synthesized
from nitrogen gas and hydrogen gas in the Haber Process . The equation for its
production is given by;
The forward reaction is
exothermic, so, according to the Le Chatelier's Principle low temperature will
favor forward reaction. But Lower temperatures decrease the reaction rates and
for maximum yield of ammonia, temperatures between 380 and 450-degree
centigrade are used.
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When you are provided
with the following data and you are required to plot a graph of temperature versus
equilibrium. Describe the shape of the graph for ammonia production. What can you predict from the graph?
From the graph, as the
temperature increases, the equilibrium drops abruptly according to the Van’t
Hoff Equation. Van’t Hoff equation is an equation that shows the relationship
among the temperature (T), equilibrium constant (Kq) changes and particular
change in standard enthalpy.
The catalyst used in
the production of ammonia gives maximum yield when the temperature (at least
400-degree centigrade) is applied. In the graph, equilibrium constant increases
as the temperature decreases. To produce the maximum amount of ammonia other parameters
(pressure and product removal) must be considered.
Pressure
Increasing the amount
of pressure favors the forward reaction. In the equation, 4 moles of reactants
are consumed to yield two moles of products. Pressures between 200-250
atmospheres are usually applied for maximum production. Even though, maintaining high pressure is
expensive and dangerous, working at 200 atm ensure the process is safe and
economical. The high amount of energy applied in running pumps and compressors make the process to produce 15% of ammonia in one pass.
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Product
removal
Removing ammonia from the system increases its
production. Ammonia is removed from the gaseous equilibrium mixture coming out
from the reaction vessel. The hot gaseous mixture is cooled promptly to enable
ammonia to condense and to be removed in liquid form. The unreacted gasses (nitrogen
and hydrogen) are recycled in the process.
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